Publications

115Nanobowls from Amphiphilic Core–Shell Cyclic Bottlebrush Polymers

Digvijayee Pal, John B. Garrison, Zhihui Miao, Lily E. Diodati, Adam S. Veige, and Brent S. Sumerlin, Macromolecules. 2022. Link
114N-heterocyclic carbene platinum-butadiyne Click/iClick complexes. Towards blue-violet phosphorescence

Ru He, Jhonti Chakraborty, Tanjila Islam, Hadi D. Arman, Wendell P. Griffith, Adam S. Veige, Kirk S. Schanze, Science Direct. Vol. 976, 2022, 122440. Link
jacs_180x52113Isolation of an Elusive Phosphametallacyclobutadiene and Its Role in Reversible Carbon−Carbon Bond Cleavage

V. K. Jakhar, A. M. Esper, I. Ghiviriga, K. A. Abboud, C. Ehm, A. S. Veige, Angew. Chem. Int. Ed. 2022, e202203073; Angew. Chem. 2022, e202203073. Link
jacs_180x52112A High-Throughput Approach to Repurposing Olefin Polymerization Catalysts for Polymer Upcycling

Felicia D. Cannavacciuolo, Rinku Yadav, Alec Esper, Antonio Vittoria, Giuseppe Antinucci, Francesco Zaccaria, Roberta Cipullo, Peter H. M. Budzelaar, Vincenzo Busico, Georgy P. Goryunov, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Keith Searles, Christian Ehm,*and Adam S. Veige*. Angew. Chem. Int. Ed., 2022. Link
111Ring-Expansion Polymerization of Cycloalkenes and Linear Alkynes by Transition Metal Catalysts

Kubo, T.; Yadav, R.; Veige, A. S. In Topological Polymer Chemistry, Concepts and Practices, Ed. Tezuka, Y. Deguchi, T. Springer Nature Singapore, Singapore, 2022. Link
110Semi-conducting cyclic copolymers of acetylene and propyne

Miao, Z.; Esper, A. M.; Nadif, S.; Gonsales, S.; Sumerlin, B. S.;* Veige, A. S.* React. Funct. Polym. 2021, 169, 105088. Link
109Double Tethered Metallacyclobutane Catalyst for Cyclic Polymer Synthesis

Mandal, U.; Ghiviriga, I.; Abboud, K. A.; Lester, Daniel W.; Veige, A. S. J. Am. Chem. Soc., 2021. Link
108Soluble polymer precursors via REMP for the synthesis of cyclic polyacetylene

Miao, Z.; Konar, D.; Sumerlin, B. S.*; Veige, A. S.* Macromolecules, 2021Link
107SPAAC iClick: Progress towards a biorthogonal reaction incorporating metal ions

Shen, Y-H.; Esper, A. M.; Ghiviriga, I.; Abboud, K. A.; Schanze, K. A.; Ehm, C.*; Veige, A. S.* Dalton Trans., 2021,50, 12681-12691. Link
106Probing ß-alkyl elimination and selectivity in polyolefin hydrogenolysis through DFT

Kane, A. Q.; Esper, A. M.; Searles, K. S.; Ehm, C.*; Veige, A. S.* Catal. Sci. Technol., 2021,11, 6155-6162. Link

105Cyclic Polyaceteylene

Miao, Zhihui; Gonsales, Stella A.; Ehm, Christian; Mentink-Vigier, Frederic; Bowers, Clifford R.; Sumerlin, Brent S.*; Veige, Adam S.*; Nature Chem., 2021. Link
104Precise NMR Method for Titering Oranometal Reagents

Jakhar, Vineet; Johnson, Eric C.; Kavuturu, Aditya; Heller, Jessica K.; Veige, Adam S.; Ghiviriga, Ion*; Org. Lett., 2021. Link
103Tethered Tungsten-Alkylidenes for the Synthesis of Cyclic Polynorbornene via Ring Expansion Metathesis: Unprecedented Stereoselectivity and Trapping of Key Catalytic Intermediates

Jakhar, Vineet; Pal, Digvijayee; Ghiviriga, Ion; Abboud, Khalil A.; Lester, Daniel W.; Sumerlin, Brent S.; Veige, Adam S.*; JACS, 2021, 143(2), 1235-1246. Link
102Ultra-High-Molecular-Weight Macrocyclic Bottlebrushes via Post-Polymerization Modification of a Cyclic Polymer

Pal, Digvijayee; Miao, Zhihui; Garrison, John B.; Veige, Adam S.*; Summerlin, Brent S.*; Macromolecules, 2020. Link
101Cyclic Poly(4-methyl-1-pentene): Efficient Catalytic Synthesis of a Transparent Cyclic Polymer

Miao, Zhihui; Pal, Digvijayee; Niu, Weijia; Kubo, Tomohiro; Sumerlin, Brent S.*; Veige, Adam S.*; Macromolecules, 2020. Link
100Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-​Based Rigid Trianionic ONO3- Pincer-​Type Ligand

Mandal, Ushnish; VenkatRamani, Sudarsan; Ghiviriga, Ion; Abboud, Khalil A.; Veige, Adam S.*; Organometallics, 2020, 39(12), 2207-2213. Link
99Excited-​State Turn-​On of Aurophilicity and Tunability of Relativistic Effects in a Series of Digold Triazolates Synthesized via iClick

Zeman, Charles J.; Shen, Yu-Hsuan; Heller, Jessica K.; Abboud, Khalil A.; Schanze, Kirk S.; Veige, Adam S.*; JACS, 2020, 142(18), 8331-8341. Link
98An Application Exploiting Aurophilic Bonding and iClick to Produce White Light Emitting Materials

Beto, Christopher C.; Zeman, Charles J.; Yang, Yajing; Bullock, James D.; Holt, Ethan D.; Kane, Alexander Q.; Makal, Trevor A.; Yang, Xi; Ghiviriga, Ion; Schanze, Kirk S.; Veige, A.S.*; , Inorg. Chem., 2020, 59(3), 1893-1904. Link
97Veige, A.S.; Roland, C. D Metallacyclopentadiene Initiators for Cyclic Polymer Synthesis from Alkynes, PCT/US20/20745 (2019). Link
96Roland, C.; Zhang, T.; VenkatRamani, S.; Ghiviriga, I.; Veige, A.S.*; A catalytically relevant intermediate in the synthesis of cyclic polymers from alkynes, Chem. Commun., 2019, 55, 13697-13700. Link
95Chakraborty, J.; Mandal, U.; Ghiviriga, I.; Abboud, K. A.; Veige, A.S.*; Ammonia Synthesis through Hydrolysis of a Trianionic Pincer-type Supported Molybdenum-Nitride Complex, Chem-Eur. J. 2019, 25, 14059-14063. Link
94Zhihui, M.; Tomohiro, K.; Digvijayee, P.; Sumerlin, B. S.*; Veige, A. S.*; pH-Responsive Water-Soluble Cyclic Polymer. Macromolecules, 2019, 52, 6260-6265. Link
93Beto, C. C.; Yang, Y.; Zeman, C. J.; Ghiviriga, I.; Schanze, K. S.*; Veige, A. S.*; Cu-Catalyzed Azide-Pt-Acetylide Cycloaddition: Progress toward a Conjugated Metallopolymer via iClick. Organometallics, 2018, 37, 4545-4550. Link
92Roland, C. C.; VenkatRamani, S.; Jakhar, V. K.; Ghiviriga, I.; Aboud, K. A.; Veige, A. S.*; Synthesis and Characterization of a Molybdenum Alkylidyne Supported by a Trianionic OCO3– Pincer Ligand. Organometallics, 2018, 37, 23, 4500-4505. Link
91

Veige, Adam S.; Jakhar, Vineet K.; Jan, Muhammad Tariq; Compositions and methods for stereoregular ring expansion metathesis polymerization, PCT Int. Appl., 2019, WO 2019108969 A1 20190606.

90

Veige, A. S.; Alkyne-​derived cyclic polyolefin composition and method for production of cyclic polyolefin., U.S. Pat. Appl. Publ., 2019, US 20190092884 A1 20190328.

89

Veige, A. S.; Macrocyclic polyalkanes, macrocyclic polyalkane-​alkenes, and related methods, PCT Int. Appl., 2019, WO 2019060090 A1 20190328.

88

Veige, A. S.; Alkyne-​derived cyclic polyolefin composition and method for production of cyclic polyolefin., PCT Int. Appl., 2019, WO 2019058192 A1 20190328.

87Niu, W.; Gonsales, S. A.; Kubo, T.; Bentz, K. C.; Pal, D.; Savin, D. A. Sumerlin, B. S.;* Veige, A. S.* Polypropylene: now available without chain ends. Chem, 2018, 5(1), 237-244. Link
86

Veige, A. S.; Gonsales, S. A.; Catalyst for Ring Expansion Metathesis Polymerization of Cyclic Monomers. U.S. Patent App. Pub. 0257065 A1 September 13, 2018. National Science Foundation supported

85

“Aptamer-mediated selective delivery of a cytotoxic cationic NHC-Au(I) complex to cancer cells” Weijia Niu, I-Ting Teng, Xigao Chen, Weihong Tan, Adam S. Veige. Dalton Trans. accepted Link

“Aptamer-mediated selective delivery of a cytotoxic cationic NHC-Au(I) complex to cancer cells” Weijia Niu, I-Ting Teng, Xigao Chen, Weihong Tan, Adam S. Veige. Dalton Trans. accepted Link

jacs_180x5284“A New Synthetic Route to In-Chain Metallopolymers via Copper(I) Catalyzed Azide-Platinum-Acetylide iClick.”C. C. Beto,E. D. Holt, Y. Yang, I. Ghiviriga,K. S. Schanze, and A. S. Veige. Chem. Commun., 2017,53, 9934-9937 Link
83

Veige, A. S.; Gonsales, S. A.; Aptamer conjugates with N-​heterocyclic carbene metal complexes for targeted drug delivery, U.S. Patent Appl. Publ., 2017, US 20170107516 A1 20170420.

82

Veige, Adam S.; Almeida Gonsales, Stella; Catalyst for ring expansion metathesis polymerization of cyclic monomers, PCT Int. Appl., 2017, WO 2017049270 A1 20170323.

jacs_180x5281
“Single versus double Cu(I) catalyzed [3+2] azide/platinum diacetylide cycloaddition reactions.” Yang, Xi.; VenkatRamani, Sudarsan; Beto, Christopher; Del Castillo, Trevor; Ghiviriga, Ion.; Abboud, K. A.; Veige, A. S. Organometallics, 2017, 36 (7), pp 1352–1357 Link
jacs_180x5280
“Trianionic Pincer Complexes of Niobium and Tantalum as Precatalysts for ROMP of Norborene.” VenkatRamani, S.; Roland, C.; Zhang J.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S. Organometallics, 2016, 35, 2675-2682. LinkSud
79“Crystal structures of a novel NNN pincer ligand and its dinuclear titanium(IV) alkoxide pincer complex.” Pedziwiatr, J.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S. Acta, Cryst. 2017, E73, 122-126. Link
chemrev78 β-Alkyl Elimination: Fundamental Principles and Some Applications.” O’Reilly, M. E.; Dutta, S.; Veige, A. S. Chem. Rev. 2016, 116, 8105-8145. Linkb-alkyl elim
jacs_180x5277“Carbon dioxide cleavage across a tungsten-alkylidyne bearing a trianionic pincer-type ligand.” Gonsales, S. A.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S. Dalton Trans., 2016, 45, 15783 – 15785. LinkStellaDalton
chemscirev76 “Solid State Collapse of a High-Spin Square-Planar Fe(II) Complex, Solution Phase Dynamics, and Electronic Structure Characterization of an Fe(II) Dimer” Matias E. Pascualini, Sebastian A. Stoian, Andrew Ozarowski, Khalil A. Abboud, and Adam S. Veige. Inorg. Chem., 2016, 55, 5191-5200 LinkFeII
jacs_180x5275“Introducing ‘ynene’ metathesis: ring-expansion metathesis polymerization (REMP) leads to highly cis and syndiotactic cyclic polymers of norborene” Nadif, S. S.; Kubo, T.; Gonsales, S. A.; VenkatRamani, S.; Ghiviriga, I.; Sumerlin, B. S.; Veige, S. A. JACS, 2016, 138, 6408-6411. LinkSouf
jacs_180x5274“N-Heterocyclic Carbene Gold(I) Complexes Conjugated to a Leukemia Specific DNA-Aptamer for Targeted Drug Delivery” Weijia Niu, Xigao Chen, Weihong Tan, Adam S. Veige. Angew. Chem. Int. Ed., 2016. LinkWeija
jacs_180x5273“Highly Tactic Cyclic Polynorbornene: Stereoselective Ring Expansion Metathesis Polymerization of Norbornene Catalyzed by a New Tethered Tungsten-Alkylidene Catalyst” Gonsales, S. A.; Kubo, T.; Flint, M. K.; Abboud, K. A.; Sumerlin, B. S.; Veige, S. A. JACS, 2016,138, 4996-4999. Link101021jacs6b00014
jacs_180x5272“Cyclic polymers from alkynes.” Roland, C. D.; Li, H. Abboud, K. A.; Wagener, K. B.; Veige, A. S. Nature Chem., 2016, 8, 791-796. Link69
jacs_180x5271“Synthesis and Characterization of a Family of M2+ Complexes Supported by a Trianionic ONO3- Pincer-type Ligand: Towards the Stabilization of High-Spin Square-Planar Complexes.” Pascualini, M. E.; Stoian, S. A.;* Ozarowski, A.; Di Russo, N. V.; Thuijs, A. E.; Abboud, K. A.; Christou, G.; Veige, A. S. Dalton Trans., 2015, 44, 20207-20215. Link.68
jacs_180x5270“Remote Multiproton Storage within a Pyrrolide-Pincer-Type Ligand” Soufiane S. Nadif, Matthew E. OÏReilly, Ion Ghiviriga, Khalil A. Abboud, and Adam S. Veige. Angew. Chem. Int. Ed., 2015, 54, 15138–15142. Link.67
jacs_180x5269“A New ONO3- Trianionic Pincer Ligand with Intermediate Flexibility and its Tungsten Alkylidene and Alkylidyne Complexes” Sudarsan VenkatRamani, Ion Ghiviriga, Khalil A. Abboud, and Adam S. Veige. Dalton Trans., 2015, 44, 18475-18486. Link66
jacs_180x5268“Expanding iClick to group 9 metals” C.C. Beto, X. Yang, A.R. Powers, I. Ghiviriga, K.A. Abboud, A.S. Veige. Polyhedron, 2015, 108, 87-92. Link.65
jacs_180x5267“Evidence for a zwitterionic transition state in double bond rotations within tungsten–vinyl complexes.” S. A. Gonsales, M. E. Pascualini, I. Ghiviriga and A. S. Veige. Chem. Commun., 2015, 51, 13404-13407. Link64
66

Veige, Adam Steven; Sarkar, Soumya; McGowan, Kevin Patrick; Kuppuswamy, Subramaniam; Roland, Christopher D.; Metallacycloalkylene complexes and use for alkyne polymerization to cyclic polyacetylenes., PCT Int. Appl., 2015, WO 2015191571 A1 20151217.

jacs_180x5265“Au-iClick mirrors the mechanism of copper catalyzed azide–alkyne cycloaddition (CuAAC).” Andrew R. Powers, Ion Ghiviriga, Khalil A. Abboud and Adam S. Veige. Dalton Trans., 2015, 44, 14747-14752. Link.63
jacs_180x5264“New Alkylidyne Complexes Featuring a Flexible Trianionic ONO3– Pincer-Type Ligand: Inorganic Enamine Effect versus Sterics in Electrophilic Additions.” Sudarsan VenkatRamani , Nicholas B. Huff , Muhammad Tariq Jan , Ion Ghiviriga , Khalil A. Abboud , and Adam S. Veige. Organometallics, 2015, 34, 2841–2848 . Link62
jacs_180x5263“Organogold oligomers: exploiting iClick and aurophilic cluster formation to prepare solution stable Au4 repeating units.” Xi Yang, Shanshan Wang, Ion Ghiviriga, Khalil A. Abboud and Adam S. Veige. Dalton Trans., 2015, 44, 11437-11443. Link61
jacs_180x5262“Fast “Wittig-Like” Reactions As a Consequence of the Inorganic Enamine Effect” Stella A. Gonsales , Matias E. Pascualini , Ion Ghiviriga , Khalil A. Abboud , and Adam S. Veige JACS, 2015, 137, 4840–4845. Link60
61“Synthesis and Characterization of Group 4 Trianionic ONO3– Pincer-Type Ligand Complexes and a Rare Case of Through-Space 19F–19F Coupling” Soufiane S. Nadif, Jakub Pedziwiatr, Ion Ghiviriga, Khalil A. Abboud, and Adam S. Veige Organometallics, 2015, 34, 1107–1117. Link
chemscirev60“Synthesis, Characterization, and Reactivity of Iron(III) Complexes Supported by a Trianionic ONO3- Pincer Ligand” Matias E. Pascualini, Natali V. Di Russo, Pedro A. Quintero, Annaliese E. Thuijs, Dawid Pinkowicz, Khalil A. Abboud, Kim R. Dunbar, George Christou, Mark W. Meisel, and Adam S. Veige Inorg. Chem., 2014, 24, 13078-13088. Link
59

Veige, Adam Steven; Falkowski, Joseph Michael; O’Reilly, Matthew; Kuppuswamy, Subramaniam; Mcgowan, Kevin P.; Sarkar, Soumya; Trianionic pincer ligands, a cr(iii)​/cr(v) catalytic system and its use for catalytic aerobic oxidation of organic substrates., U.S. Pat. Appl. Publ., 2014, US 8846950 B2 20140930.

58“N-heterocyclic carbene gold(I) and silver(I) complexes bearing functional groups for bio-conjugation” Mary E. Garner, Weijia Niu, Xigao Chen, Ion Ghiviriga, Khalil A. Abboud, Weihong Tana and Adam S. Veige Dalton Trans., 2015, 44, 1914-1923. Link57b
chemscirev57“A High-Spin Square-Planar Fe(II) Complex Stabilized by a Trianionic Pincer-Type Ligand and Conclusive Evidence for Retention of Geometry in Solution” Matias E Pascualini, Natalie V di Russo, Annaliese Thuijs, Andrew Ozarowski, Sebastian A Stoian, Khalil A Abboud, George Christou and Adam Steven Veige Chem. Sci., 2015, 6, 608-612. Link
chemscirev56“Trianionic pincer and pincer-type metal complexes and catalysts” Matthew E. O’Reilly, and Adam S. Veige. Chem Soc Rev, 2014, 43, 6325-6369. Link55
Organometallics55
“Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Supported by a New Pyrrolide-Centered Trianionic ONO3– Pincer-Type Ligand” Matthew E. O’Reilly, Soufiane S. Nadif, Ion Ghiviriga, Khalil A. Abboud, and Adam S. Veige. Organometallics, 2013, 33, 836-839. Link
Polyhedron54
“Synthesis and characterization of trianionic pincer-type complexes of tantalum(V) including solid (X-ray) and solution (NMR) state assignment of an intraligand N–H—F hydrogen bonding interaction” Sudarsan VenkatRamani, Matias E. Pascualini, Ion Ghiviriga, Khalil A. Abboud, and Adam S. Veige. Polyhedron, 2013, 64, 377-387. Link This article is part of the special issue edited by Gerard Parkin, dedicated to Prof. George Christou on the occasion of his 60th birthday.
53
“Inorganic click (iClick) synthesis of heterotrinuclear PtII/AuI2 complexes” Andrew R. Powers, Xi Yang, Trevor J. Del Castillo, Ion Ghiviriga, Khalil A. Abboud, and Adam S. Veige. Dalton Trans., 2013, 42, 14963-14966. Link
52
“Human cancerous and healthy cell cytotoxicity studies of a chiral µ-dicarbene-digold(I) metallamacrocycle.” Amrita B. Mullick, Yun Min Chang, Ion Ghiviriga, Khalil A. Abboud, Weihong Tan, and Adam S. Veige. Dalton Trans., 2013, 42, 7440-7446. Link
51

Veige, Adam Steven; Jeletic, Mathew S.; Lowry, Roxy J.; Abboud, Khalil A.; Catalysts containing n-​heterocyclic carbenes for enantioselective synthesis., U.S. Pat. Appl. Publ., 2013, US 8455661 B2 20130604.

50
“Unusually stable tungstenacyclobutadienes featuring an ONO trianionic pincer-type ligand.” Matthew E. O’Reilly, Ion Ghiviriga, Khalil A. Abboud, and Adam S. Veige. Dalton Trans., 2012, 42, 3326-3336. Link Article being highlighted on the Dalton Transactions BLOGS website as a HOT article!Link
Chemical Science49
“Compelling mechanistic data and identification of the active species in tungsten-catalyzed alkyne polymerizations: conversion of a trianionic pincer into a new tetraanionic pincer-type ligand.” Kevin P. McGowan, Matthew E. O’Reilly, Ion Ghiviriga, Khalil A. Abboud, and Adam S. Veige. Chemical Science, 2012, 4, 1145-1155. Link Article being highlighted on the Chemical Science website as a HOT article! Link
Polyhedron48
“Convenient in situ generation of a chiral bis-carbene palladium catalyst from a dibenzimidazolium salt precursor and Pd(OAc)2 and its application in enantioselective synthesis.” Amrita B. Mullick, Matthew S. Jeletic, Andrew R. Powers, Ion Ghiviriga, Khalil A. Abboud, and Adam S. Veige. Polyhedron, 2013, 52, 810-819. Link
JACS47
“A New ONO3- Trianionic Pincer-Type Ligand for Generating Highly Nucleophilic Metal-Carbon Multiple Bonds” O’Reilly, M. E.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S. J. Am. Chem. Soc., 2012, 134, 11185–11195. Link
JOMC46
“A neutral trianionic pincer [NCN]CrIV–Me complex as a highly active ethylene polymerization precatalyst.” McGowan, K. P.; Veige, A. S.* J. Organomet. Chem., 2012, 711, 10-14. Link
JACS45
“An OCO3– Trianionic Pincer Tungsten(VI) Alkylidyne: Rational Design of a Highly Active Alkyne Polymerization Catalyst.” Sarkar, S.; McGowan, K. P.; Kuppuswamy, S.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S.* J. Am. Chem. Soc., 2012, 123, 4509-4512. Link
44
“The influence of reversible trianionic pincer OCO3- µ-oxo CrIV dimer formation ([CrIV]2(µ-O)) and the role of donor ligands in oxygen-atom-transfer (OAT).” O’Reilly, M. E.; Del Castillo, T. J.; Abboud, K. A.; Veige, A. S. Dalton Trans., 2012, 41, 2237-2246. (Hot Article, Cover Art) Link
U.S. Patent and Trademark Office43“Cr(III)/Cr(V) catalytic system and its use for aerobic oxidation of organic substrates.” Veige, A. S.; Falkowski, J. M.; O’Reilly, M. U.S. Provisional Patent Application No US-2011-0313174-A1, 2011. Link
Organometallics42
“Chemical Exchange Saturation Transfer (CEST) as a Quantitative Tool to Measure Ligand Flexibility of Chelating Chiral di-N-Heterocyclic Carbene Complexes” Jeletic, M. S.; Lower, C. E.; Ghiviriga, I.; Veige, A. S. Organometallics, 2011, 30, 6034-6043. Link
U.S. Patent and Trademark Office41“Trianionic pincer tungsten-alkylidyne complexes for alkyne metathesis and alkyne polymerization.” Sarkar, S.; Kuppuswamy, S.; McGowan, K. P.; Veige, A.S.* U.S. Provisional Patent Application No UF 13916, 2011.
Organometallics40 “Trianionic NCN3- pincer complexes of chromium in four oxidations states (CrII, CrIII, CrIV, CrV): determination of the active catalyst in selective 1-alkene to 2-alkene isomerization.” McGowan, K. P.; Abboud, K. A.; Veige, A. S. Organometallics, 2011, 30, 4949-4957. Link40b
JOMC39 “Synthesis and characterization of a trianionic pincer supported Mo-alkylidene anion and alkyne insertion into a Mo(IV)-Cpincer bond to form metallocyclopropene(?2-vinyl) complexes.” Jan, M. T.; Sarkar, S.; Kuppuswamy, S.; Ghiviriga, I.; Veige, A. S. J. Organomet. Chem., 2011, ASAP. Link39b
U.S. Patent and Trademark Office38“ONO pincer ligands and ONO pincer ligand comprising metal complexes.” O’Reilly, M. E.; Jan, M. T.; Veige, A. S. US. Provisional Patent Application No UF.952P 2011. Link
JACS37
“Autocatalytic O2 cleavage by an OCO3- trianionic pincer CrIII complex: isolation and characterization of the autocatalytic intermediate [CrIV]2(µ-O) dimer.” O’Reilly, M. E.; Del Castillo, T. J.; Falkowski, J. M.; Ramachandran, V.; Pati, M. Correia, M. C.; Abboud, K. A.; Dalal, N. S.; Richardson, D. E.; Veige, A. S. J. Am. Chem. Soc., 2011, 133, 13661-13673. Link
JOMC36
“Synthesis and characterization of ?-2-bis-N-heterocyclic carbene rhodium(I) catalysts: application in enantioselective arylboronic acid addition to cyclohex-2-enones.” Jeletic, M. S.; Lowry, R. J.; Swails, J. M.; Ghiviriga, I.; Adam S. Veige J. Organomet. Chem., 2011, 696, 3127-3134. Link
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“1,3-Dipolar cycloaddition between a metal-azide (Ph3PAuN3) and a metal-acetylide (Ph3PAuC=CPh): an inorganic version of a click reaction.” Del Castillo, T. J.; Sarkar, S.; Abboud, K. A. Veige, A. S. Dalton Trans., 2011, 40, 8140-8144. Link
Angewandte34 “Primary carbon-nitrogen bond scission and methyl dehydrogenation across a W-W multiple bond.” Sarkar, S.; Culver, J. A.; Peloquin, A. J.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S. Angew. Chemie., Int. Ed., 2010, 50, 9711-9714. Link34b
Inorganic Chemistry33
“NCN Trianionic pincer ligand precursors: synthesis of bimetallic, chelating diamide, and trianionic group IV complexes.” Sarkar, S.; McGowan, K. P.; Culver, J. A.; Carlson, A. R.; Koller, J.; Peloquin, A. J.; Veige, M. K.; Abboud, K. A. Veige, A. S. Inorg. Chem., 2010, 49, 5143-5156. Link
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“A new chiral di-N-heterocylic carbene (NHC) cyclophane ligand and its application in palladium enantioselective catalysis.” Jeletic, M. S.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S. Dalton Trans., 2010, 39, 6392-6394. Link
NHC Book: Catalysis by Metal Complexes31“Chapter 9: Reactions involving CO.” Jeletic, M. S.; Veige, A. S. In Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis, Cazin, C. S. J., Ed., 2010, Springer: (Invited contribution). Link
Organometallics30
“Activation of an aryl C-H bond converts chelating diphenolate ligands bound to zirconium into trianionic pincer ligands s-donor ligand effects versus thermolysis.” Kuppuswamy, S.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S.* Organometallics, 2010, 29, 6711-6722. Link
Organometallics29
“Synthesis and characterization of tungsten(VI) alkylidene complexes supported by an [OCO]3- trianionic pincer ligand: progress towards the [tBuOCO]W=CC(CH3)3 fragment.” Kuppuswamy, S.; Peloquin, A. J.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S. Organometallics, 2010, 29, 4227-4233. Link
U.S. Patent and Trademark Office28“Method for linking two or more metal metals for photo and electronic materials.” Veige, A. S.; Murray, J. L.; Del Castillo, T. J. U.S. Provisional Patent Application No UF.952P, 2010. Link
Inorganic Chemistry27
“Catalytic aerobic oxidation by a trianionic pincer CrIII/CrVO couple.” O’Reilly, M.; Falkowski, J. M.; Ramachandran, V.; Pati, M.; Abboud, K. A.; Dalal, N. S.; Gray, T. G.; Veige, A. S. Inorg Chem., 2010, 48, 10901-10903. Link
U.S. Patent and Trademark Office26“Single component catalysts for olefin polymerization and isomerization.” Veige, A. S.; McGowan K. P. U.S. Provisional Patent Application No UF.951P, 2010. Link
Polyhedron25
“The next generation of C2-symmetric ligands: a di-N-heterocyclic carbene (NHC) ligand and the synthesis and X-ray characterization of mono- and dinuclear rhodium(I) and iridium(I) complexes.” Lowry, R. J.; Jan, M. T.; Abboud, K. A.; Ghiviriga, I.; Veige, A. S. Polyhedron, 2009, 29, 553-563. (Special Young Investigator Next Generation Issue). Link
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“New iridium and rhodium chiral di-N-heterocyclic (NHC) complexes and their application in enantioselective catalysis: explanations for catalyst performance.” Jeletic, M. J.; Jan, M. T.; Ghiviriga, I; Abboud, K. A.; Veige, A. S. Dalton Trans., 2009, 2764-2776. Link
U.S. Patent and Trademark Office23“Method for transferring N-atoms from metal complexes to organic and inorganic substrates.” Veige, A. S.; Sarkar, S. U.S. Provisional Patent Application No UF 12843, 2009. Link
JACS22
“Addition of mild electrophiles to a Mo=N triple bond and nitrile synthesis via metal-mediated N-atom transfer to acid chlorides.” Sarkar, S.; Abboud, K. A.; Veige, A. S. J. Am. Chem. Soc., 2008, 130, 16128-16129. Link
U.S. Patent and Trademark Office21“Preparation of N-heterocyclic carbene catalysts for enantioselective catalysis.” Veige, A. S.; Jeletic, M. S.; Lowry, R. J. PCT Int. Appl. WO 2008-US54137, 2008. Link
Organometallics20
“New constrained-geometry C2-symmetric di-N-heterocyclic carbene ligands and their mono- and dinuclear rhodium(I) complexes: design, synthesis, and structural analysis.” Lowry, R. J.; Veige, M. K.; Clément, O.; Abboud, K. A.; Ghiviriga, I.; Veige, A. S. Organometallics, 2008, 27, 5184-5195. Link
Polyhedron19
“Carbon monoxide as a reagent: a report on the role of N-Heterocyclic carbene (NHC) ligands in metal-catalyzed carbonylation reactions.” Veige, A. S. Polyhedron, 2008, 27, 3177-3189 (Invited Review). Link
JACS18
“Synthesis, Characterization, and Reactivity of a d2, Mo(IV) Complex Supported by a New OCO-Trianionic Pincer Ligand.” Sarkar, S. Carlson, A. R.; Veige, M. K.; Falkowski, J. M.; Abboud, K. A.; Veige, A. S. J. Am. Chem. Soc., 2008, 130, 1116-1117. Link
Organometallics17
“Mono- and bimetallic rhodium(I) complexes supported by new C2-symmetric bis-N-heterocyclic carbene ligands: metalation via C=C bond cleavage under mild conditions.” Jeletic, M. S.; Ghiviriga, I.; Abboud, K. A.; Veige, A. S. Organometallics, 2007, 26, 5267–5270. Link
Organometallics16
“Synthesis and characterization of (2,6-iPrNCN)HfCl2– and (3,5-MeNCN)2Hf2– (where NCN = 2,6-bis[phenylazanidyl]methylphenyl): new trianionic pincer ligands.” Koller, J.; Sarkar, S. Abboud, K. A.; Veige, A. S. Organometallics, 2007, 26, 5438–5441. Link
  1. “Intermolecular C–H bond activation and redox isomerization across two-electron mixed valence diiridium cores.” Esswein, A. J.; Veige, A. S.; Piccoli, P. M. B.; Schultz, A. J.; Nocera, D. G. Organometallics, 2008, 27, 1073-1083.
  1. “PC bond cleavage of (silox)3NbPMe3 (silox = tBu3SiO) under dihydrogen leads to (silox)3Nb=CH2, (silox)3Nb=PH or (silox)3NbP(H)Nb(silox)3, and CH4.” Hirsekorn, F. F.; Veige, A. S.; Wolczanski, P. T. J. Am. Chem. Soc., 2006, 128, 2192-2193.
  1. “A photocycle for hydrogen production from two-electron mixed-valence complexes.” Esswein, A. J.; Veige, A. S.; Nocera, D. G.* J. Am. Chem. Soc., 2005, 127, 16641-16651.
  1. “Thermodynamics, kinetics, and mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) rearrangements (silox = tBu3SiO; M = Nb, Ta).” Hirsenkorn, K. F.; Veige, A. S.; Marshak, M.; Koldobskaya, Y.; Wolczanski, P. T.*; Cundari, T. R.; Lobkovsky, E. B. J. Am. Chem. Soc., 2005, 127, 4809-4830.
  1. “Hydrogenation of Two–Electron Mixed–Valence Iridium Alkyl Complexes.” Veige, A. S.; Gray, T. G.; Nocera, D. G.* Inorg. Chem., 2005, 44, 17-26.
  1. “Oxygen and hydrogen photocatalysis by two–electron mixed–valence coordination.” Rosenthal, J.; Bachman, J.; Dempsey, J. L.; Esswein, A. J.; Gray, T. G.; Hodgkiss, J. M.; Manke, D. R.; Luckett, T. D.; Pistorio, B. J.; Veige, A. S.; Nocera, D. G.* Coord. Chem. Rev., 2005, 249, 1316-1326.
  1. “Cooperative bimetallic chemistry: hydrogen addition in two-electron mixed-valence compounds.” Gray, T. G.; Veige, A. S.; Nocera, D. N. J. Am. Chem. Soc., 2004, 126, 9760-9768.
  1. “Water addition to a two-electron mixed-valence bimetallic center.” Veige, A. S.; Nocera, D. G.* Chem. Commun., 2004, 17, 1958-1959.
  1. “Symmetry and geometry consideration of atom transfer: deoxygenation of (silox)3WNO and R3PO (R = Me, Ph, tBu) by (silox)3M (M = V, NbL (L = PMe3, 4-Picoline), Ta; silox = tBu3SiO.” Veige, A. S.; Slaughter, L. M.; Lobkovsky, E. M.; Wolczanski, P. T.*; Matsunaga, N.; Decker, S. A.; Cundari, T. R. Inorg. Chem., 2003, 42, 6204-6224.
  1. “Amide derivatives of tantalum and a niobium–promoted ring opening of 3,5–lutidine.” Bonanno, J. B.; Veige, A. S.; Wolczanski, P. T.*; Lobkovsky, E. B. Inorganica Chemica Acta., 2003, 345, 173-184.
  1. “(silox)3RePMe3 (silox = tBu3SiO) is carbonylated to the double insertion product (silox)(Me3P){cis-(CO)2}Re{trans-((CO2SitBu3)2}.” Veige, A. S.; Wolczanski, P. T.*; Lobkovsky, E. B. Chem. Commun., 2001, 24, 2734-2735.
  1. “Dehydrogenation of {(silox)3Nb}2(n-1,2; n-5,6-C8H8)] (silox = tBu3SiO) to {(silox)3Nb)2(n-1,2; n-5,6-C8H6)] and its subsequent alkene-to-alkylidene rearrangement.” Veige, A. S.; Wolczanski, P. T.*; Lobkovsky, E. B. Angew. Cehm., Int. Ed. Engl., 2001, 40, 3629-3632.
  1. “Deoxygenations of (silox)3WNO and R3PO by (silox)3M (M = V, Ta) and (silox)3NbL (silox = tBu3SiO): consequences of electronic effects.” Veige, A. S.; Slaughter, L. M.; Wolczanski, P. T.*; Matsunaga, N.; Decker, S. A.; Cundari, T. R. J. Am. Chem. Soc., 2001, 123, 6419-6420.
  1. “(Silox)3Nb(?2-N.C-4-picoline) as a source of (silox)3Nb: structure of [(silox)3Nb]2(µ-?2,?2-C6H6) (silox = tBu3SiO).” Veige, A. S.; Kleckley, T. S.; Chamberlin, R. M.; Neithamer, D. R.; Lee, C. E.; Wolczanski, P.T.*; Lobkovsky, E. B.; Glassey, W. V. J. Organomet. Chem., 1999, 591, 194-203.
  1. “Structural dichotomy in six-coordinate d0 complexes: trigonal prismatic (tBu3SiC=C)6Ta- and octahedral (tBu3SiCC)6M2- (M = Zr, Hf).” Vaid, T.P.; Veige, A. S.; Lobkovsky, E. B.; Glassey, W.V.; Wolczanski, P. T.*; Liable–Sands, L. M.; Rheingold, A.L.; Cundari, T. R. J. Am. Chem. Soc., 1998, 120, 10067-10079.